Next-Generation Battery Research, July 28-29 2020, Orlando FL

Cambridge EnerTech’s

Next-Generation Battery Research

Advances in Chemical, Material, and Electrochemical Engineering

MARCH 9-10, 2021 | ALL TIMES EASTERN STANDARD (UTC-05:00)


Have lithium-ion batteries (LIBs) reached their technical limit? A revolutionary paradigm is required to design new stable anode, cathode and electrolyte chemistries and engineer separator materials to provide LIBs with higher energy, higher power, longer lifetime and superior safety. Coordinated efforts in fundamental research and advanced engineering are needed to effectively combine new materials, electrode architectures, and manufacturing technologies.

Tuesday, March 9

INCREASING ENERGY DENSITY: ELECTRODES

9:00 am

Oxygen Release and Degradation Mechanisms in Cathodes for Li-Ion Batteries

Reza Shahbazian-Yassar, PhD, Associate Professor Mechanical & Industrial Engineering, Civil & Materials Engineering, University of Illinois Chicago
9:20 am

Recent Progress in Understanding the Mechanical and Electrochemical Properties of Low/No-Cobalt Layered Cathodes

Feng Lin, PhD, Assistant Professor, Chemistry, Virginia Polytechnic Institute & State University

The interplay between electrochemical and mechanical properties influences the nanoscale charge distribution in battery particles and their contributions to the overall battery capacity. Crystallographic defects such as dislocations and grain boundaries have a huge impact on the charging behavior and mechanical properties of single-crystal and polycrystalline battery particles. This presentation covers our recent progress in probing and designing defect chemistries to improve Li-ion cathode materials, including NMC811 and LNO.

9:40 am

Unlocking Multiphysics Design Guidelines on Si/C Composite Nanostructures for High-Energy-Density and Robust Lithium-Ion Battery Anode

Jun Xu, PhD, Professor, Mechanical Engineering & Engineering Science, University of North Carolina, Charlotte

In general, current material fabrication guidance for novel designs of Si/C composite particle materials focuses on electrochemical behavior and redox reactions at the nano/micro level. However, such guidances cannot provide detailed information for predicting mechanical deformations of the composite particles. Here, we establish an electro-chemo-mechanical model and implement it to quantitatively analyze
the multiphysics behavior of five representative Si/C composite nanostructures.

10:00 am Session Break - View Our Virtual Exhibit Hall
Guozhong Cao, PhD, Boeing Steiner Professor, Materials Science & Engineering, University of Washington

In this presentation, I will share with you some of our recent work on tailoring the local atomic structure in layer-structured vanadate through pre-insertion of alien ions or removal or substitution of constituent ions or molecules to attain high storage capacity, improved kinetics, as well as energy conversion efficiency. It also demonstrated improved stability and reversibility of cathode materials. 

10:40 am

Precursor Vapor Phase Processing of Battery Components

Anil Mane, PhD, Principal Materials Science Engineer, Applied Materials Division, Argonne National Laboratory

Ultrathin ALD coating method has shown promises for Li-ion batteries performance improvement such as suppression of transition metal dissolution and degassing, cyclability improvement and lower area selective impendence scattering.  This presentation covers ALD/CVD precursor vapor phase processing for battery components (e.g. anode, cathode and solid state electrolytes). Additionally I will also present our recent work on fundamental studies of ALD Al2O3 and AlF3 ultrathin coatings on various battery base materials.

 

Nicolo Brambilla, Chief Technology Officer, Nanoramic Laboratories
11:40 am MODERATED Q&A:

Session Wrap-Up

Panel Moderator:
Jun Xu, PhD, Professor, Mechanical Engineering & Engineering Science, University of North Carolina, Charlotte
Panelists:
Guozhong Cao, PhD, Boeing Steiner Professor, Materials Science & Engineering, University of Washington
Nicolo Brambilla, Chief Technology Officer, Nanoramic Laboratories
Feng Lin, PhD, Assistant Professor, Chemistry, Virginia Polytechnic Institute & State University
Anil Mane, PhD, Principal Materials Science Engineer, Applied Materials Division, Argonne National Laboratory
Reza Shahbazian-Yassar, PhD, Associate Professor Mechanical & Industrial Engineering, Civil & Materials Engineering, University of Illinois Chicago
12:05 pm Session Break - View Our Virtual Exhibit Hall

PLENARY KEYNOTE PROGRAM

12:50 pm

A Micrometer Can Tell You a Lot about Li-Ion Cell Failure Modes

Jeff Dahn, FRSC, PhD, Professor of Physics and Atmospheric Science, NSERC/Tesla Canada Industrial Research Chair, Canada Research Chair, Dalhousie University

Sure, fancy methods like synchrotron X-ray tomography, scanning ultrasonic imaging, and differential capacity analysis can really help one understand the reasons for Li-ion cell failure.  However, once one understands the basic processes, measurements made with a simple micrometer can give a pretty decent idea of why Li-ion pouch cells fail.   I will use an extensive study on a large matrix of NMC622/graphite cells tested for 2.5 years at different temperatures, C-rates and depths of discharge to illustrate the importance of a simple micrometer.  

1:15 pm

U.S. Department of Energy Initiatives to Develop and Advance Lithium Batteries

David Howell, Program Manager, Acting Director, Office of Vehicle Technologies, United States Department of Energy

DOE supports research to develop EV batteries that (1) cuts battery cell cost to $60/kWh, (2) reduces battery weight and size enabling higher efficiency EVs, (3) enables 15-minute charging time, and (4) supports the development of a lithium battery recycling ecosystem. DOE chairs the Federal Consortium for Advanced Batteries that brings Federal together to accelerate the development of a robust secure domestic industrial base and ecosystem for advanced batteries.

2:00 pm MODERATED KEYNOTE Q&A:

Session Wrap-Up

Panel Moderator:
Brian Barnett, PhD, President, Battery Perspectives
Panelists:
Jeff Dahn, FRSC, PhD, Professor of Physics and Atmospheric Science, NSERC/Tesla Canada Industrial Research Chair, Canada Research Chair, Dalhousie University
David Howell, Program Manager, Acting Director, Office of Vehicle Technologies, United States Department of Energy
2:25 pm Session Break - View Our Virtual Exhibit Hall

INCREASING ENERGY DENSITY: MATERIALS AND MEMBRANES

2:45 pm

Through Thick and Thin – Can High-Capacity Thin-Film Win the Solid-State War?

Richard Clark, Global Lead, Energy Storage, Morgan Advanced Materials

The vast majority of work on solid-state is based around oxide, sulfide or polymer electrolytes. While deposition processes are well-established for fabrication of micro-batteries, they are not currently considered economically viable for high-capacity batteries. Novel technology from Demaray LLC is changing that, showing that high energy density and long cycle life cells made by deposition processes can be cost-effective – this new approach is poised to disrupt several key markets.

3:05 pm

Ceramic-Modified Separators Designed to Push the Limits of Cell Performance

Richard W. Pekala, ScD, CTO, R&D, Entek International LLC

Ceramic-filled separators offer extremely low impedance in combination with excellent wettability. In contrast, ceramic-coated separators provide excellent in-plane, high temperature dimensional stability in combination with shutdown of the polyolefin base separator. This work examines the influence of ceramic filler and coating compositions, particle size distributions, and loading levels on the thermomechanical and electrical properties of battery separators designed for large format Li-ion or rechargeable Li-metal based cells.

3:25 pm

Lithium-Ion Battery Separators for Ionic-Liquid Electrolytes

Adam S. Best, Principal Research Scientist, CSIRO Manufacturing

In developing new electrolytes for lithium-ion and next-generation batteries, there is a need to develop innovative separator solutions to maximise cell performance and, where possible, address safety aspects surrounding the interaction between the electrolyte and electrodes. In this presentation, we will discuss some of our work on the development of innovative separators, thermal studies of electrode | electrolyte combinations and the implications for cell safety.

David Potter, Marketing Director, Marketing, Luna Innovations, Inc.

Successful design and manufacturing of advanced battery technologies depend heavily on accurate and thorough characterization of thermal and structural performance. While thermocouples and other traditional methods can provide the minimal measurements needed, fiber optic sensors offer advanced capabilities with unmatched data coverage, usability and safety. Learn how distributed fiber optic sensing systems can be deployed within cells, packs and modules to deliver new levels of critical data and insight.

4:25 pm MODERATED Q&A:

Session Wrap-Up

Panel Moderator:
Richard Clark, Global Lead, Energy Storage, Morgan Advanced Materials
Panelists:
Adam S. Best, Principal Research Scientist, CSIRO Manufacturing
Richard W. Pekala, ScD, CTO, R&D, Entek International LLC
David Potter, Marketing Director, Marketing, Luna Innovations, Inc.
4:50 pm Session Break - View Our Virtual Exhibit Hall
5:10 pm Interactive Roundtable Discussions

The roundtables are informal, moderated discussions with brainstorming and interactive problem solving, allowing participants from diverse backgrounds to exchange ideas and experiences and develop future collaborations around a focused topic. Each topic is led by a moderator who ensures focused conversation around the key issues of that topic. Attendees choose to join a specific group.

ROUNDTABLE 1: Battery Materials Supply Chain

Robert M. Privette, Manager, Business Development, Rechargeable Battery Materials North America, Umicore USA Inc.
  • Financing challenges (Economics, Uncertainty, Contracting)
  • Supply & availability (Long supply chains, New capacity timelines)
  • Sustainability and lifecycle analysis (Role of renewables, Customer awareness)

ROUNDTABLE 2: The Future Direction of the Binder Market in the Wake of the Silicon Anode

Manuel Wieser, Head of Energy Division, AnteoTech
  • Silicon anode active material market is set to quadruple from 2020 to 2030
  • Performance requirements for anode binders are changing rapidly (considering low to high silicon content anode designs)
  • Binder material evolution: SBR functionalization, vs. PAA derivatization vs. return to organic solvent-based binders?
  • Surface chemistry challenge: Various silicon anode systems with different surface properties (SiOx, micro-silicon, silicon-carbon composites,…)
  • Greater diversification in future binder market or is one-size fits it all possible?​

ROUNDTABLE 3: Benefits and Challenges of Cell Manufacturing Software for Prototype and Full Scale Manufacturing

Bob Zollo, Solution Architect for Battery Testing, Keysight Technologies
  • How can software for cell formation/grading help improve cell quality and increase production yield on prototype manufacturing lines and on full scale manufacturing lines.
  • Data analytics role in helping to manufacture better cells.
  • The value of bringing and test data from characterization labs together with manufacturing data collected from upstream processes, formation/grading, and downstream processes.

ROUNDTABLE 4: Commercially Viable Process for Surface Conditioning of High-Ni Cathodes

Feng Wang, PhD, Materials Scientist, Energy & Photon Sciences Directorate, Brookhaven National Lab
  • What is the start-of-the-art and next generation of high-Ni cathodes? And what are other options to further push on Li-storage capacity  -- ultra-high Ni, Co-free, or other new cathode systems?
  • Besides thermal instability, safety-related issues, what are other key barriers hindering the commercial use of high-Ni cathodes?
  • What are the most commonly employed processes in industry for surface conditioning of high-Ni cathodes?
  • What are other processes that are promising for industrial use in stabilizing high-Ni cathodes?
5:55 pm Close of Day

Wednesday, March 10

INCREASING ENERGY DENSITY: ELECTROLYTES

9:00 am

Realizing Zinc Metal as a Rechargeable Battery Electrode

Marshall Schroeder, PhD, Materials Engineer, Battery Science Branch, DEVCOM Army Research Laboratory

Rechargeable batteries with a zinc metal anode offer a promising and sustainable alternative to existing lithium-ion and emerging lithium metal batteries for specialized energy storage applications of the future. This talk will cover some of the critical factors dictating Zn reversibility and a perspective of the technology status through the lens of published research in the field.

Wu Xu, PhD, Chief Scientist, Energy & Environment, Pacific Northwest National Lab

In response to the challenges conventional LiPF6/carbonate electrolytes face in lithium-ion batteries (LIBs), especially in terms of safety, low/high temperature performances, long cycling/calendar stability, etc., functional localized high-concentration electrolytes (LHCEs) have been developed for LIBs. Due to the unique solvation structure of LHCEs, LHCEs lead to formation of thin, compact and uniform electrode/electrolyte interphases, thus greatly improving LIB performances. More details will be reported during the presentation. 

9:40 am

Lithium-Ion Battery Electrolyte Degradation of Field-Tested Electric Vehicle Battery Cells – A Comprehensive Analytical Study

Sascha Nowak, PhD, Head of Analytics & Environmental, Electrochemical Energy Technology, University of Münster

Electrolytes from lithium-ion battery cells of field-tested electric vehicles of several original equipment manufacturers were investigated by complementary analytical techniques, giving insights into the feasibility of analysis electrolytes beyond the lab-scale. The application of a whole series of established analytical methods allowed to comprehensively analyze LIB electrolytes and provided reliable conclusions about the different cell chemistries.

10:00 am

The Dilemma of Faster Charging and More Energy-Dense Lithium-Ion Batteries

David Hall, PhD, Research Associate, Chemistry, University of Cambridge

Lithium-ion batteries have become ubiquitous in daily life, finding use for an increasingly wide range of applications. As their intended uses become more diverse, so too do the specifics of cell design. This presentation will discuss the oxidative stability and reaction behaviour of electrolyte solutions for faster charging and more energy-dense cell designs.

Mike Sandoval, Vice President, Business Development, Maccor, Inc.

Battery testing simplified for new and non-technical people supporting the battery industry.  Topics covered include the differences between Resistance and Impedance, Electrochemical Impedance Spectroscopy (EIS) and Direct Current Internal Resistance (DCIR) and many more topics.

11:00 am MODERATED Q&A:

Session Wrap-Up

Panel Moderator:
Sascha Nowak, PhD, Head of Analytics & Environmental, Electrochemical Energy Technology, University of Münster
Panelists:
David Hall, PhD, Research Associate, Chemistry, University of Cambridge
Marshall Schroeder, PhD, Materials Engineer, Battery Science Branch, DEVCOM Army Research Laboratory
Wu Xu, PhD, Chief Scientist, Energy & Environment, Pacific Northwest National Lab
Mike Sandoval, Vice President, Business Development, Maccor, Inc.
11:25 am Close of Next-Generation Battery Research Conference